The top gong was won by the real madrid star again with Diego Simeone named Coach of the Year.
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The Real Madrid star was named the best player from last season in Spain's top flight after scoring 31 goals in just 30 league games for the European champions.
The Ballon d'Or holder becomes only the second player to win the prize since its inception in 2008-09, with Lionel Messi having won all five of the previous titles.
"I have to thank my team-mates, Real Madrid, my family... it is a very good moment in my career," Ronaldo, also named best forward of the season, said at the awards ceremony in Madrid.
"For me, the important thing is to win collective prizes, but I like the individual ones, too. I work every day, in training, to continue adding more to this."
As well as the best player and best forward awards, Ronaldo made it a hat-trick by scooping the prize for best goal of the campaign for his strike against Valencia in week 36.
Diego Simeone was honoured as best coach after guiding Atletico Madrid to the title in a remarkable season which also saw them reach the Champions League final.
"I want to share this with my players, without whom none of this would be possible," said the Argentine. "Thanks to Koke, Gabi, Miranda, Courtois... and everyone who made it possible to win the title."
Keylor Navas, now of Madrid, picked up the best goalkeeper accolade for his stunning season with Levante. Sergio Ramos scooped the best defender award and Luka Modric was best defensive midfielder on a successful night for Carlo Ancelotti's players.
Barcelona's Andres Iniesta was best attacking midfielder, while Carlos Bacca (best South American) and Yacine Brahimi (best African) were also recognised. Rafinha Alcantara was named the revelation of the campaign.
The awards for the best players and coach were voted for by the three team captains of each side in the division, though they were not allowed to vote for players from their own club. La Liga coaches chose the revelation award, while internet polls were responsible for the best goal, best African and best South American prizes.
| AWARD | WINNER | CLUB |
| Best Player | Cristiano Ronaldo | Real Madrid |
| Best Coach | Diego Simeone | Atletico Madrid |
| Best Goalkeeper | Keylor Navas | Real Madrid (formerly Levante) |
| Best Defender | Sergio Ramos | Real Madrid |
| Best Defensive Midfielder | Luka Modric | Real Madrid |
| Best Attacking Midfielder | Andres Iniesta | Barcelona |
| Best Forward | Cristiano Ronaldo | Real Madrid |
| Best African Player | Yacine Brahimi | Granada |
| Best South American Player | Carlos Bacca | Sevilla |
| Revelation | Rafinha Alcantara | Barcelona (loaned to Celta in 2013-14) |
| Best Goal | Cristiano Ronaldo (vs Valencia) | Real Madrid |
| Fair Play | Ivan Rakitic | Barcelona (formerly Sevilla) |
